Preparative and spectroscopic studies of some sulphur halide species

Askew, Herbert Frank

(1981)

Askew, Herbert Frank (1981) Preparative and spectroscopic studies of some sulphur halide species.

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Abstract

Raman spectra of trichlorosulphonium tetrachloroaluminate, SCl3+ AlCl4, and hexachloroantimonate, SCl3+ SbCl6-, are in agreement with previously reported work. Two complexes of the noveltribromosulphonium cation, SBr3+ AlX4 (X = Cl, Br), have been prepared and Raman spectra assigned on the basis of a pyramidal, C3v, SBr3+ ion. Mixing solid trichloro-and tribromosulphonium tetrachloroaluminates produced a solid containing mixed chlorobromosulphonium cations, SClnBr3-n+ AlCl4- (O

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This is a Accepted version
This version's date is: 1981
This item is not peer reviewed

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https://repository.royalholloway.ac.uk/items/e67a29df-9b91-4808-bb54-fcd2cb2f15cc/1/

Item TypeThesis (Doctoral)
TitlePreparative and spectroscopic studies of some sulphur halide species
AuthorsAskew, Herbert Frank
Uncontrolled KeywordsInorganic Chemistry; Pure Sciences; Halide; Preparative; Some; Species; Spectroscopic; Studies; Sulfur Halides; Sulphur; Sulfur Halides
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Identifiers

ISBN978-1-339-61565-3

Deposited by () on 01-Feb-2017 in Royal Holloway Research Online.Last modified on 01-Feb-2017

Notes

Digitised in partnership with ProQuest, 2015-2016. Institution: University of London, Royal Holloway College (United Kingdom).


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