A thermodynamic investigation of some alkali-metal polyhalide compounds

Peake, Stuart John

(1976)

Peake, Stuart John (1976) A thermodynamic investigation of some alkali-metal polyhalide compounds.

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Abstract

An isoperibol solution reaction calorimeter has been constructed. The precision and accuracy of the calorimeter were checked by measuring the enthalpy of reaction of tris(hydroxymethyl)aminomethane, THAM, in:(a) excess 0.1 mol dm - aqueous hydrochloric acid(b) excess 0.05 mol dm -3 aqueous sodium hydroxide. The mean of 8 runs were: (a) DeltaH298 (1296 2-,C103-,Br03- and I0 3 have been calculated to investigate the relationshipbetween the 'thermochemical radius' and the geometric size of an ion of given symmetry. Lattice energies of alkali-metal and alkaline-earth salts containing these ions have been estimated and compared with literature values

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This is a Accepted version
This version's date is: 1976
This item is not peer reviewed

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https://repository.royalholloway.ac.uk/items/b0ea98e2-d159-44f4-90d2-cbb3cbd2be71/1/

Item TypeThesis (Doctoral)
TitleA thermodynamic investigation of some alkali-metal polyhalide compounds
AuthorsPeake, Stuart John
Uncontrolled KeywordsMolecular Physics; Pure Sciences; A; Alkali; Compounds; Investigation; Metal; Polyhalide; Polyhalides; Polyhalides; Some; Thermodynamic
Departments

Identifiers
ISBN978-1-339-61497-7

Deposited by () on 01-Feb-2017 in Royal Holloway Research Online.Last modified on 01-Feb-2017

Notes

Digitised in partnership with ProQuest, 2015-2016. Institution: University of London, Royal Holloway College (United Kingdom).

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